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Astron. Astrophys. 346, 285-294 (1999)
2. Laboratory wavelength measurements
Measurements of the wavelengths of emission lines of highly ionized
species are a considerable experimental challenge and have been
performed only at very few laboratories. We will first study the
literature data available for the transitions
of the
Ne ion. Kelly (1987) lists
wavelengths of 770.409 Å and 780.324 Å for the
Ne VIII resonance lines and cites the references
Edlén (1963) and Bockasten et al. (1963). The same rest
wavelengths are given in the National Institute of Standards and
Technology catalogue (NIST, 1995). Edlén in his report refers
to Bockasten and co-workers, and thus no independent data points have
been established. The first laboratory observations of the
Ne VIII lines by Fawcett et al. (1961) gave wavelengths
of 770.42 Å and 780.34 Å with uncertainties of
30 mÅ. They were obtained with a normal-incidence vacuum
spectrograph and a high-temperature (a few 100 eV) deuterium
plasma with neon as trace element. The large Doppler width caused by
the high temperature limited the accuracy of this measurement.
Bockasten et al. used the high-current toroidal discharge apparatus
SCEPTRE IV as light source and a modified Hilger E 793 3-m
normal-incidence vacuum spectrograph with a plate factor of
2.78 Å mm-1 in first order. The authors
estimate the uncertainty of their Ne VIII
( 770) wavelength determination to be
5 mÅ. We will,
although this is not mentioned in the original publication, assume a
1- level for this uncertainty. No
justification is given for the uncertainty estimate, but the same
uncertainty levels are given for the O VI
( 1031.945, 1037.627) and
F VII ( 890.762) lines.
In the latter three cases, Kelly (1987) quotes values of
1031.924 Å, 1037.614 Å, and
890.786 Å, respectively, taken from the following sources:
Ryabtsev (1975), Edlén (1934), and Palenius (1971). Brown
(1980) measured the wavelengths of the O VI lines from
spectrograms taken with the 6.6-m vacuum spectrograph at the Naval
Research Laboratory (NRL), Washington, and found 1031.929 Å
and 1037.617 Å with uncertainties of
5 mÅ each. If we
attach the same credibility to the later measurements as to the
earlier ones, it follows that the uncertainty estimates of Bockasten
et al. were too optimistic in three cases, and, therefore, it can
safely be assumed that the estimate for Ne VIII was
also too confident. Based on the root-mean-square (RMS) values of the
deviations established for the lines O VI and
F VII , we estimate an uncertainty of
18 mÅ
(1 ) for Ne VIII
( 770.409). The wavelength of the
N V ( 1238) line, given
with an uncertainty margin of 10 mÅ by Bockasten et al.
(1963), was later reported to be 16 mÅ longer (Hallin
1966), another indication that the uncertainty levels of Bockasten et
al. were too narrow.
Despite a careful literature search, no other calculations or
laboratory measurements have been found, which could improve our
knowledge on the important Ne VIII wavelength. The
situation is much more favourable for UV lines emitted by neutral
species or ions not so highly ionized. Eriksson and Isberg (1968)
estimated the accuracy for O I UV line measurements to
be 2 mÅ and for
calculations 0.5 mÅ
or better. We will use 144 Si I and four
C I lines in the wavelength interval from
1531.6 Å to 1552.2 Å given by Kelly (1987) in
our comparison and, in addition, the Fe II
( 1550.260) and the N II
( 775.965) lines. In particular, we
will synthesize a spectrum in this range from all these lines with the
help of their relative intensities after noting that the intensity
values agree with our observations for isolated lines and after
adjusting the C I , Fe II , and
N II intensity scales to the Si I one.
All lines were assumed to have Gaussian profiles. A line width of
134 mÅ (FWHM) was chosen according to our measurements. The
spectrum was built up in wavelength steps of 1 mÅ. Most of
the Si I lines referenced by Kelly are taken from Brown
et al. (1974) and Moore et al. (1977). The wavelength uncertainties
quoted are 5 mÅ,
however, in general, the wavelengths are in agreement with other
sources to within
3 mÅ. The
corresponding C I data stem from Kaufman & Ward
(1966) with uncertainties of
1 mÅ. The source for
the C I observations was a water-cooled copper hollow
cathode. The spectra were obtained with a 10.7-m Eagle-type vacuum
spectrograph having a first-order reciprocal dispersion of
0.78 Å mm-1. Johansson (1966) calculated
wavelengths of C I UV lines and estimated the
uncertainties to be less than 2 mÅ.
© European Southern Observatory (ESO) 1999
Online publication: May 6, 1999
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